Partner: A. Herczyński


Recent publications
1.Gabriele V.R., Shvonski A., Hoffman C.S., Giersig M., Herczyński A., Naughton M.J., Kempa K., Towards spectrally selective catastrophic response, PHYSICAL REVIEW E, ISSN: 2470-0045, DOI: 10.1103/PhysRevE.101.062415, Vol.101, pp.062415-1-6, 2020
Abstract:

We study the large-amplitude response of classical molecules to electromagnetic radiation, showing the universality of the transition from linear to nonlinear response and breakup at sufficiently large amplitudes. We demonstrate that a range of models, from the simple harmonic oscillator to the successful Peyrard-Bishop-Dauxois type models of DNA, which include realistic effects of the environment (including damping and dephasing due to thermal fluctuations), lead to characteristic universal behavior: formation of domains of dissociation in driving force amplitude-frequency space, characterized by the presence of local boundary minima. We demonstrate that by simply following the progression of the resonance maxima in this space, while gradually increasing intensity of the radiation, one must necessarily arrive at one of these minima, i.e., a point where the ultrahigh spectral selectivity is retained. We show that this universal property, applicable to other oscillatory systems, is a consequence of the fact that these models belong to the fold catastrophe universality class of Thom's catastrophe theory. This in turn implies that for most biostructures, including DNA, high spectral sensitivity near the onset of the denaturation processes can be expected. Such spectrally selective molecular denaturation could find important applications in biology and medicine.

Affiliations:
Gabriele V.R.-other affiliation
Shvonski A.-other affiliation
Hoffman C.S.-other affiliation
Giersig M.-IPPT PAN
Herczyński A.-other affiliation
Naughton M.J.-other affiliation
Kempa K.-other affiliation
2.Herczyński A., Herczyński R., Kozłowski A., Determination of the differential cross section for a realistic intermolecular potential, PHYSICAL REVIEW E, ISSN: 1539-3755, DOI: 10.1103/PhysRevE.51.266, Vol.51, No.1, pp.266-272, 1995
Abstract:

A method for obtaining the differential cross section for any realistic intermolecular potential (e.g., the Lennard-Jones potential), is presented. This approach avoids ad hoc approximations, such as the finite-range potentials and angular cutoffs, and can be used for accurate calculations of the transport coefficients. It is shown that neither the hard spheres nor the soft spheres (variable hard spheres) models are consistent with a realistic potential, even in the limit of large relative molecular velocity.

Affiliations:
Herczyński A.-other affiliation
Herczyński R.-IPPT PAN
Kozłowski A.-IPPT PAN