| Partner: S.N.F Yusuf |
Ostatnie publikacje
| 1. | Nazir S.♦, Singh P.♦, Rawat N.♦, Jain A., Michalska M.♦, Yahya M.♦, Yusuf S.♦, Diantoro M.♦, Polyether (polyethylene oxide) derived carbon electrode material and polymer electrolyte for supercapacitor and dye-sensitized solar cell, Ionics, ISSN: 0947-7047, DOI: 10.1007/s11581-024-06052-9, pp.1-11, 2025 Streszczenie: This study investigates the development and performance analysis of a supercapacitor using activated carbon synthesized from polyethylene oxide (PEO) as the electrode material, and a poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP)-based polymer electrolyte, prepared using a solution-cast technique for dye-sensitized solar cell (DSSC) application. This paper deals with polyether-based electrochemical devices, where electrode material is developed by polyethylene oxide (PEO), while an electrolyte is prepared using PVdF-HFP. Detailed electrical and photoelectrochemical studies were carried out using various characterization tools, and the results are discussed in detail. Sandwich structure supercapacitors and DSSCs are developed using maximum conducting polymer electrolyte that has an ionic conductivity of (8.3 × 10−5) Scm−1, exhibiting a high specific capacitance of 395 Fg−1 and DSSC efficiency ranging from 1.6 to 3.5% under 1 sun condition. The findings underscore the capability of PEO-derived carbon and polymer electrolytes in improving the efficiency of energy storage and conversion systems. Słowa kluczowe: Polyether, Activated carbon, Supercapacitor, Dye-sensitized solar cell Afiliacje autorów:
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| 2. | Nazir S.♦, Singh P.♦, Jain A., Michalska M.♦, Yahya M.♦, Yusuf S.♦, Diantoro M.♦, Latif F.♦, Singh M.♦, Polyether-Derived Carbon Material and Ionic Liquid (Tributylmethylphosphonium iodide) Incorporated Poly(Vinylidene Fluoride-co-Hexafluoropropylene)-Based Polymer Electrolyte for Supercapacitor Application, Journal of Energy Storage, ISSN: 2352-152X, DOI: 10.1002/est2.70083, Vol.6, No.8, pp.1-15, 2024 Streszczenie: Poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP)-sodium thiocyanate (NaSCN) solid polymer electrolytes containing different weight ratios of ionic liquid (IL)—tributylmethylphosphonium iodide (TBMPI) were prepared using solution-cast approach. Electrochemical impedance data indicates that increasing ionic liquid into polymer electrolyte matrix increases ionic conductivity and the maximum value of ionic conductivity was obtained at 150 wt% TBMPI, having conductivity value of 8.3 × 10−5 S cm−1. The dielectric measurement supports our conductivity data. Ionic transference number measurement affirms this system to be predominantly ionic in nature, while electrochemical stability window (ESW) was found to be 3.4 V. Polarized optical microscopy (POM) along with differential scanning calorimetry (DSC) suggest suitability of TBMPI as plasticizer, while infrared spectroscopy (FTIR) confirms ion interaction, complexation, and composite nature. The thermogravimetric analysis (TGA) shows thermal stability of these ionic liquid-doped polymer electrolytes (ILDPEs). Using maximum conducting ILDPE, a sandwiched supercapacitor has been fabricated which shows stable performance as high as 228 Fg−1 using cyclic voltammetry (CV). Słowa kluczowe: capacitance, ionic conductivity, ionic liquid (IL), solid polymer electrolyte (SPE), supercapacitor (SC) Afiliacje autorów:
| | 100p. |