Institute of Fundamental Technological Research

In the article, as a result of comparative tests, it is established that steel samples with a coating applying the electrospark alloying method (ESA) with a BK6 hard-alloy electrode with the use of a special technological environment (STE) with a composition of 0.5%Si + 0.5%B + 2%Cr + 7%Ni + 90% vaseline, the wear of which after 24 hours of testing is of 221 mg that is 122% less than that for samples without coating and 15% and 31% for samples with coatings applying the nichrome-electrodes’ wire X20H80 using STE composition of 0.5%Si + 0.5%B + 59%BK6 + 40% vaseline and STE composition of 5%Si + 5%B + 90% vaseline, respectively, and by 22% and 47% less than with coatings applying the electrodes made by the method of powder metallurgy (PM), the composition of which is of 90%BK6 + 10%1M and 1M, respectively. For P6M5 steel, better resistance against hydroabrasive wear is possessed by samples with a coating applying the ESA method with an electrode made of hard alloy BK6 using STE composition of 0.5%Si + 0.5%B + 2%Cr + 7%Ni + 90% vaseline, the wear of which after 24 hours of testing is of 188 mg that is 43% less than in samples without coating and by 6% and 15% in samples with a coating applying the ESA method with an electrode made of nichrome wire of the composition X20H80 using STE composition of 0.5%Si + 0.5%B + 59%BK6 + 40% vaseline and STE composition of 5%Si + 5%B + 90% vaseline, and by 24% and 27% less than with coatings applying the electrodes produced by the PM method with a composition of 90%BK6 + 10%1M and 1M, respectively. In ESA with electrodes-tools made both by the PM method and by the new technology of wire X20H80 and hard alloy BK6 and STE, parts made of steel 45 and steel P6M5 have a decrease in the strength limit and yield limit, respectively, and both the relative elongation and the relative narrowing increase. With further abrasive-free ultrasonic finishing (AFUF), both the strength limit and the yield strength increase, and both the relative elongation and the relative narrowing decrease. For practical implementation, wear-resistant coatings formed according to the new technology, using tool electrodes made of X20H80 wire and hard alloy BK6 and STE in two stages with the following AFUF are proposed, the growth of the strength limit and the yield limit of which increase for steel 45 and steel P6M5 by 4.9% and 4.6% and 3.5% and 2.7%, respectively, and relative elongation and relative contraction decrease by 1.7% and 1.3% and 2.0% and 1.7%, respectively. At the same time, the surface roughness is Ra = 1.1 μm, and the integrity is of 100%

electrospark alloying, electrode tool, coating, white layer, microhardness, roughness, integrity

The article reviews and analyses the current scientific research in the field of surface treatment of metal surfaces with concentrated energy fluxes (CEF) — the electric-spark (in the literature, known also as electrospark) alloying (ESA), which makes it possible to obtain surface structures with unique physical, mechanical and tribological properties at the nanoscale. The ESA method with a graphite electrode (electrospark carburizing — EC) is based on the process of diffusion (saturation of the surface layer of a part with carbon), and it is not accompanied by an increase in the size of the part. In this article, the influence of the EC parameters on the quality of the carburized layer is investigated. The microstructural analysis shows that the three characteristic zones could be distinguished in the structure: the carburized (‘white’) layer, the finely dispersed transition zone with fine grain, and the base metal zone. The analysis of the results of the durometric studies of the coatings is carried out. To achieve the required parameters of dimensional accuracy and roughness of the working surface of the part after the EC process, it is necessary to use the method of non-abrasive ultrasonic finishing (NAUF). In addition, because of applying the NAUF method, the surface roughness is decreased, the tensile stresses are changed to the compressive ones, and the fatigue strength is increased too. In addition, to reduce the roughness of the treated surface, it is proposed to apply the EC technology in stages, reducing the energy of the spark discharge at each subsequent stage. In order to increase the quality of the carburized layer obtained by the EC process, it is proposed to use a graphite powder, which is applied to the treated surface before alloying. The comparative analysis shows that, after the traditional EC process at Wp = 4.6 J, the surface roughness of steel 20 is Ra = 8.3–9.0 μm, and after the proposed technology, Ra = 3.2–4.8 μm. In this case, the continuity of the alloyed layer increases up to 100%; there increases the depth of the diffusion zone of carbon up to 80 μm as well as the microhardness of the ‘white’ layer and its thickness, which increase up to 9932 MPa and up to 230 μm, respectively. The local micro-x-ray spectral analysis of the obtained coatings shows that, at the EC process carried out in a traditional way, the applying Wp = 0.9, 2.6, 4.6 J provides the formation of the surface layers with high-carbon content depths of 70, 100, 120 μm, respectively, and with the use of a graphite powder, they are of 80, 120, 170 μm. While deepening, the amount of carbon is decreasing from 0.72–0.86% to the carbon content in the base metal — 0.17–0.24%. In the near-surface layer formed with the use of the new technology, the pores are filled with free graphite, which could be used as a solid lubricant to improve the operating characteristics of the friction-pairs parts processed thereby

electrospark (electric-spark) alloying, graphite, carburizing, microstructure, quality, wear resistance

In article we present the results of studies of the local x-ray spectral analysis of coatings formed by the electrospark alloying (ESA) method at the discharge energy Wp = 0.13, 0.52 and 0.9 J by anodes from nickel and stainless steel X10CrNiTi18-10 on the cathode surface from X10CrNiTi18-10 steel. During ESA by stainless steel X10CrNiTi18-10 anode with an increase Wp in characteristic points and from the entire investigated surface of the coating, the quantitative elemental composition is not changed. The analysis of elements distribution over the depth of the formed layer is showed that when using the electrode tool from steel X10CrNiTi18-10 with an increase in Wp, there are a slight decrease in chromium and an increase in nickel and titanium in the surface layer. When steel X10CrNiTi18-10 is replaced by nickel with an increase in Wp, the concentration of nickel on the coating surface decreases from 95.38 to 89.04%. As the recession deepens from the coating surface, the concentration of nickel gradually decreases, respectively, at Wp = 0.13, 0.52 and 0.9 J from 96.29, 90.29 and 89.04% on the surface to 9.0, 10.30 and 9.9% at depth: 120, 165 and 240 μm. At the same time, the concentration of chromium, titanium and iron gradually increases.

electrospark alloying, nickel, steel, x-ray spectral analysis, scan step, topography, spectrum

The article substantiates the importance and relevance of increasing problem of the performance and service life of babbitt sliding bearings (SB), which are the rotors supports of a large number of centrifugal pumps, compressors, turbines and other dynamic equipment operating at high operating parameters (speeds, loads and temperatures), as well as in conditions of corrosive, abrasive and other types of working environment’s influence. The analysis of the babbitt SBs production technology and operating conditions showed that the reason for the decrease in their durability are factors that are formed both at the stage of manufacture and during operation. SB failure under normal operating conditions is a consequence of wear various types: cavitation, abrasive wear, damage due to plastic deformations, fatigue damage, etc. The antifriction layer wear resistance depends on the mode of operation and design of the bearing, the physical properties of the connection between the layer and the base, the rigidity of the shaft and the bed under the bearings. As established, the bearing anti-friction layer quality must be evaluated according to the following criteria: adhesion strength of the coating to the base, cohesive strength of the anti-friction layer, porosity, and homogeneity of the structure. As established, during the production of SBs, the formation by the method of electrospark alloying (ESA) of a copper intermediate layer, firmly bonded with steel substrate, and tin layer (formation of solid substitution solutions) and babbitt provides a stronger (by 35%) of adhesion, compared to traditional technology (steel 20 + babbitt), steel substrate with babbitt, as well as more intensive removal of heat from the friction zone. As determined, a new technology in which all operations are carried out by the ESA method can be a reserve for improving the babbitt coatings formation quality, which significantly affects the durability of the SB. As determined, in order to determine a more rational technology for applying babbitt coatings, it is necessary to develop a physically based mathematical model that relates the wear of a certain amount of babbitt to the frictional work spent on it.

sliding bearing, babbitt, coating, wear, structure, transition layer, adhesion strength, electrospark alloying, mathematical model

In the article, a direct choice system of the most rational technology for applying a babbitt coating on the liners of sliding bearings (SB) is developed, which takes into account both economic and environmental requirements. On the basis of the performed research, a physically substantiated mathematical model of the babbitt-coatings’ wear process (wear equation) is proposed, which allows solving both the direct problem of determining weight and linear wears based on the known work of friction, as well as the inverse problem of finding the necessary work of friction to obtain the required amount of weight or linear wears. With knowing the time to reach a certain amount of wear, it becomes possible to operate the products more rationally, timely assigning the repair time and friction-surface catastrophic-wear preventing. In the course of research, a methodology is developed for determining the constants of the wear equation: activation energy (EA) as well as maximum weight (Δmб.п.н) and linear (Δhб.п.н) wears, which can be used as selection criteria for the most rational technology of applying a babbitt coating.

sliding bearing, babbitt, coating, wear, structure, transition layer, adhesion strength, electrospark alloying, mathematical model

The paper analyzes the works devoted to solving problems affecting the bearing life of rolling bearings (RB) and to revealing reserves for its increase. There proposed a new technology for forming a protective coating on the shaft bearing journal or on the surface of a sleeve pressed thereon, which consists in the use of a combined technology comprising a process for stage-by-stage aluminizing by the method of electrospark alloying (A ESA ) followed by a process of ion nitriding (IN). Such a coating has a 100% continuity, the greatest thickness of the increased hardness zone of 300 µm, the surface microhardness of 7700 MPa, and the roughness (Ra) after non-abrasive ultrasonic finishing (NAUF) of 0.5 µm, The results of the X-ray microanalysis indicate that an increased content of aluminum is observed in the surface layer at the distance of up to 40 µm after the stage-by-stage AESA process. The research results have shown that in order to restore the shaft bearing journal neck surface layer hardness, which had been lost because of the repair work, the step-by-step AESA technology is more preferable. Thus, when removing the surface layer to a depth of 0.15 mm and subsequently carburizing by the method of electrospark alloying (C ESA ), the maximum microhardness of the surface layer is 7250 MPa, and the thickness of the zone of the increased hardness is 150 µm, At subsequently processing by the AESA method, these quality parameters of the surface layer are, respectively, 7350 MPa and 210 µm. The use of the NAUF method, both after C ESA and AESA processes, makes it possible to reduce the surface roughness up to Ra = 0.5 µm. To decrease the surface roughness of the RB housing seat, it is advisably to practice burnishing with a diamond tool (DB) after the A ESA process